Well, I've got some news, most of it's pretty bad, but I do have something that may cheer up at the end.
Sucky Stuff:
Turns out that the capture card has this really wierd obscure S-video slot with 8 pins - which means another purchase is needed. Not only this, but the slot at the back of the Packard Bell machine is just plain wierd, and won't be compatible with anything. This thing has just got tons more confusing. At this rate, if we ever do get the capture card working, the drivers won't work or some rubbish like that...
I've got to admit right now that it looks like we've hit a dead end with this idea, and the 96/98 rig looks like it makes more sense. Which is wierd, as before today I thought it was the other way around. This Rayman game is so finicky I can't see it working on another computer.
Alternate Explanation:
By the powers of Betilla's magic baguette - nothing is going my way!
Good Stuff:
While getting videos of this game has been an absolute disaster thus far - something that is possible and far easier to do (and not with any stupid capture cards either) is rip audio from the game. As Rayman CP has an all new soundtrack, sometime in the near future (maybe even starting today if I'm lucky) I'll be happy to get started. Menu music might be a bit awkward as it has sound effects, but anything within the activities as well as the songs with lyrics will be fine. This might even be quite a nice treat for Raytunes
EDIT: Oh and also - did you know that Betilla's favourite place to eat baguettes is on-top a washing machine?